Basu, Bharathibai J and Rajagopalan, SR (1993) Polarographic determination of trace amount of titanium13; using catalytic current in the presence of chlorate. Bulletin of Electrochemistry, 9 (1). pp. 35-37.
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Abstract
Titanium (IV) oxalate complexes are reduced catalytically in the presence of chlorate and this gives rise to an13; enhancement in sensitivity . Experimental conditions such as acid strength and the concentrations of chlorate,13; oxalate etc . were standardized to extend the linearity of calibration graph to low titanium concentrations. The13; interfering effect of other metal ions like Fe(III), Mo(VI), Cu(II), Bi(III), Pb(II), Cd(II), Ni(II), Cr(III), Cr(VI) and Zn(II) on the catalytic current of Ti(IV) was investigated . The detection limit for the determination of Ti(IV) by this method was found to be 5 ng nil-t.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Polarography;Catalytic current;Titanium;Chlorate |
| Subjects: | CHEMISTRY AND MATERIALS > Chemistry and Materials (General) |
| Depositing User: | Poornima Narayana |
| Date Deposited: | 28 Jun 2006 |
| Last Modified: | 07 Aug 2015 05:53 |
| URI: | http://nal-ir.nal.res.in/id/eprint/1995 |
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