Dilametric studies on Ge-Sb-Se classes

Mahadeva, Sudha and Giridhar, A and Narasimham, PSL and Singh, AK (1984) Dilametric studies on Ge-Sb-Se classes. Journal of Non-Crystalline Solids, 65 . pp. 233-240.

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    Abstract

    Results of measurements of the thermal expansion coefficient from room temperature up to the softening temperature on several compositions of the Ge-Sb-Se glass system are reported. The a -T data for these glasses have two region A below Tg where a is essentially constant followed by a region B around Tg where a increases with temperature. In the region A the composition dependence is identical for the three families of glasses studied, with the a-composition data showing an angularity at the corresponding stoichiometric composition of each family, while changes in a of about eighty percent are seen for compositions across a family, the change in a over the stoichiometric compositions is about fifteen per cent .An expression of the form a=za,x, where a, and x, are the expansion coefficients and weight fractions respectively of the individual structural units is found to account satisfactorily for the a-composition data of these glasses.In the region B,A increases with temperature .The increase in a is greater and begins at about 30to40 degrees lower than Tg for the SE-RICH GLASSES AS COMPARED TO THE Ge-rich glasses,where the increase is less and begins at Tg

    Item Type: Journal Article
    Additional Information: Copyright for this article belongs to Elsevier Science Publishers B.V
    Uncontrolled Keywords: Dilametric studies;Thermal expansion
    Subjects: AERONAUTICS > Aeronautics (General)
    Division/Department: Materials Science Division, Materials Science Division, Materials Science Division, Materials Science Division
    Depositing User: M/S ICAST NAL
    Date Deposited: 23 May 2008
    Last Modified: 07 May 2012 11:10
    URI: http://nal-ir.nal.res.in/id/eprint/4722

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