Crystal and molecular structure of the discogen bis[1,3-di(p-n- Decylphenyl)propane-1,3-dionato]paliadium(ll)

Usha, K and Vijayan, Kalyani and Sadashiva, BK and Rao, PR (1990) Crystal and molecular structure of the discogen bis[1,3-di(p-n- Decylphenyl)propane-1,3-dionato]paliadium(ll). Molecular Crystals and Liquid Crystal, 185. pp. 1-11.

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The transition metal containing discogen, bis[1,3-di(p-n-decylphenyl)propane-1 ,3-dionato ]paliadium(II)crystallizes in the triclinic space group pI with one molecule in a unit cell of dimensions a = 10.260(2), b = 12.961(2), c = 13.403(2)A., ex= 110.54(1), f3= 101.75(1) and 'I = 98.44(lt. The crystal structure was solved by direct methods and refined using full matrix least squares procedure. The palladium atom is lying on an inversion center. The decyl chains are fully extended in an all trans conformation. In the crystal structure, the molecules form a tilted columnar arrangement. The angle between the normal to the core and the column axis is 68xB0;. Each column is surrounded by six others. Along the13; column axis, adjacent palladium atoms are separated by 10.26A.

Item Type: Article
Additional Information: Copyright for this article belongs to Taylor amp; Francis
Uncontrolled Keywords: Discogen;Discotic mesophase;Organic ligands
Subjects: CHEMISTRY AND MATERIALS > Chemistry and Materials (General)
Depositing User: M/S ICAST NAL
Date Deposited: 16 Oct 2006
Last Modified: 24 May 2010 04:21

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