Crystal and Molecular Structure of the Discogen bis[1,3-d(p-n-octylphenyl)propane-1,3-dionato ]copper(II)

Usha, K and Vijayan, Kalyani and Sadashiva, BK (1991) Crystal and Molecular Structure of the Discogen bis[1,3-d(p-n-octylphenyl)propane-1,3-dionato ]copper(II). Molecular Crystals and Liquid Crystal, 201. pp. 13-21.

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Abstract

The transition metal containing diswgen bis[1,3-di(p-n-octylphenyl)propane-l ,3-dionato ]copper(II)13; crystallizes in the triclinic space group Pl. The copper atom lies on an inversion centre and is surrounded13; by four oxygen atoms in a square planar arrangement. The octyl chains are fully extended in an alltrans13; conformation. The molecules form a tilted columnar arrangement, the angle of tilt between the13; disc normal and the column axis being 122xB0;. The column axis coincides with the crystallographic a-axis.13; In the crystal structure, each column is surrounded by six others. Along the column axis, adjacent13; copper atoms are separated by 5.821(3)A..

Item Type: Article
Uncontrolled Keywords: Discotic;Copper complex;Crystal structure
Subjects: CHEMISTRY AND MATERIALS > Chemistry and Materials (General)
Depositing User: Users 90 not found.
Date Deposited: 27 Oct 2006
Last Modified: 24 May 2010 04:21
URI: http://nal-ir.nal.res.in/id/eprint/3021

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